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Vol. 8, Issue 3

Green Energy & Environment

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Front Cover

封面文章

清华大学程易教授课题组研究论文——Plasma treated M1 MoVNbTeO_x–CeO₂composite catalyst for improved performance of oxidative dehydrogenation of ethane

该图将文章中讲述的能量转化过程类比成接力跑的形式，不同服装的人物分别代表电能，复合催化剂，乙烷反应物和乙烯产物。通过接力的形式，表示能量从电能最终转化成反应的化学能，进而展示本文的研究思路：利用等离子体这一技术将电能间接出存在催化剂中，进而强化反应发生。

Back Cover

封底文章

福州大学赖跃坤教授、黄剑莹教授和蔡伟龙研究员团队综述——Advances in particulate matter filtration: Materials, performance, and application

01

Viewpoint

Towards a molecular understanding of the electronic metal-support interaction (EMSI) in heterogeneous catalysis

Keng Sang¹, Ji Zuo¹, Xiangxue Zhang, Qianhong Wang, Wenyao Chen*, Gang Qian, Xuezhi Duan*

https://doi.org/10.1016/j.gee.2022.12.006

Citation:K. Sang, J. Zuo, X. Zhang, Q. Wang, W. Chen, G. Qian, X. Duan,Green Energy Environ. 8 (2023) 619-625.

02

Review articles

Advances of manganese-oxides-based catalysts for indoor formaldehyde removal

Jiayu Zheng, Wenkang Zhao, Liyun Song, Hao Wang, Hui Yan, Ge Chen, Changbao Han*, Jiujun Zhang*

Recent progress of manganese oxides-based catalysts for indoor formaldehyde removal is systematically reviewed and the application of purifier and Trombe wall for HCHO catalysis were summarized.

https://doi.org/10.1016/j.gee.2022.01.008

Citation:J. Zheng, W. Zhao, L. Song, H. Wang, H. Yan, G. Chen, C. Han, J. Zhang,Green Energy Environ. 8 (2023) 626-653.

Recent advancement and future challenges of photothermal catalysis for VOCs elimination: From catalyst design to applications

Yang Yang, Shenghao Zhao, Lifeng Cui*, Fukun Bi, Yining Zhang, Ning Liu, Yuxin Wang, Fudong Liu, Chi He, Xiaodong Zhang*

A broad view of recent photothermal catalyst fabrication, applications, challenges, and prospects can be systemically provided by this review.

https://doi.org/10.1016/j.gee.2022.02.006

Citation:Y. Yang, S. Zhao, L. Cui, F. Bi, Y. Zhang, N. Liu, Y. Wang, F. Liu, C. He, X. Zhang,Green Energy Environ. 8 (2023) 654-672.

Advances in particulate matter filtration: Materials, performance, and application

Xuzheng Ji, Jianying Huang*, Lin Teng, Shuhui Li, Xiao Li, Weilong Cai*, Zhong Chen, Yuekun Lai*

Advanced filtration materials and their functions are then summarized, among which polymers and MOFs are discussed in detail together with their antibacterial performance, and the discussion on the application is divided into end-of-pipe treatment and source control.

https://doi.org/10.1016/j.gee.2022.03.012

Citation:X. Ji, J. Huang, L. Teng, S. Li, X. Li, W. Cai, Z. Chen, Y. Lai,Green Energy Environ. 8 (2023) 673-697.

Application of metal organic framework in wastewater treatment

Xiaoge Liu, Yuying Shan, Songtao Zhang, Qingquan Kong, Huan Pang*

The applications of pristine MOFs as membrane filler or membrane raw materials and adsorbents in the separation of heavy metals, dyes and antibacterials from wastewater have been reviewed. The pristine MOFs demonstrate huge potential in sustainable wastewater treatment.

https://doi.org/10.1016/j.gee.2022.03.005

Citation:X. Liu, Y. Shan, S. Zhang, Q. Kong, H. Pang,Green Energy Environ. 8 (2023) 698-721.

Tuning the selectivity of natural oils and fatty acids/esters deoxygenation to biofuels and fatty alcohols: A review

Yingdong Zhou, Javier Remón*, Zhicheng Jiang, Avtar S. Matharu, Changwei Hu*

This review presents the recent progress achieved in the catalytic deoxygenation of natural oils or related model compounds (e.g., fatty acids) to renewable liquid fuels (green diesel and bio-jet fuels) and valuable fatty alcohols (unsaturated and saturated fatty alcohols).

https://doi.org/10.1016/j.gee.2022.03.001

Citation:Y. Zhou, J. Remón, Z. Jiang, A.S. Matharu, C. Hu,Green Energy Environ. 8 (2023) 722-743.

03

Research papers

Are Ni/ and Ni₅Fe₁/biochar catalysts suitable for synthetic natural gas production? A comparison with γ-Al₂O₃supported catalysts

M. González-Castaño*, C. Morales, J.C. Navarro de Miguel, J.H. Boelte, O. Klepel, J.I. Flege, H. Arellano-García

Taking Ni and NiFe catalysts supported over γ-Al₂O₃oxide as reference materials, this work evaluates the potentiality of Ni and NiFe supported biochar catalysts for CO₂methanation. The development of competitive biochar catalysts was found dependent on the creation of basic sites on the catalyst surface.

https://doi.org/10.1016/j.gee.2021.05.007

Citation:M. González-Castaño, C. Morales, J.C. Navarro de Miguel, J.H. Boelte, O. Klepel, J.I. Flege, H. Arellano-García,Green Energy Environ. 8 (2023) 744-756.

Aluminum-air battery with cotton substrate: Controlling the discharge capacity by electrolyte pre-deposition

Wending Pan, Yifei Wang*, Holly Y.H. Kwok, Dennis Y.C. Leung*

A low-cost, lightweight and pumpless aluminum-air battery using alkaline-deposited cotton as electrolyte substrate was developed, whose discharge lifetime can be precisely controlled by the alkaline loading inside cotton, eliminating the Al corrosion loss after battery usage.

https://doi.org/10.1016/j.gee.2021.05.003

Citation:W. Pan, Y. Wang, H.Y.H. Kwok, D.Y.C. Leung,Green Energy Environ. 8 (2023) 757-766.

Novel in-capsule synthesis of metal–organic framework for innovative carbon dioxide capture system

Wei Yu, Ming Gao, Guanhe Rim, Tony G. Feric, Mark L. Rivers, Ammar Alahmed, Aqil Jamal, Ah-Hyung Alissa Park*

This study focuses on a novel MOF-based hybrid sorbent that is for the first time produced via an innovative in-situ encapsulated synthesis with glass double-capillary devices. The developed MOF-bearing microcapsules were characterized by various tools and tested for CO₂capture.

https://doi.org/10.1016/j.gee.2021.08.002

Citation:W. Yu, M. Gao, G. Rim, T.G. Feric, M.L. Rivers, A. Alahmed, A. Jamal, A.-H. Alissa Park,Green Energy Environ. 8 (2023) 767-774.

A purely green approach to low-cost mass production of zeolitic imidazolate frameworks

Hai Li¹, Wan Chen¹, Bei Liu*, Mingke Yang¹, Zixuan Huang, Changyu Sun, Chun Deng, Dapeng Cao*, Guangjin Chen*

This work report an unconventional method suitable for environmentally friendly and low-cost mass-production of ZIFs. This method is really green as no waste gas or liquid generates because CO₂and water could be recycled perfectly.

https://doi.org/10.1016/j.gee.2021.09.003

Citation:H. Li, W. Chen, B. Liu, M. Yang, Z. Huang, C. Sun, C. Deng, D. Cao, G. Chen,Green Energy Environ. 8 (2023) 775-784.

Au^δ−–O_v–Ti³⁺: Active site of MO_x-Au/TiO₂catalysts for the aerobic oxidation of 5-hydroxymethylfurfural

Weiyao Yang¹, Mengchen Fu¹, Chenyu Yang, Yiwen Zhang, Chun Shen*

A series of metal oxide modified MO_x-Au/TiO₂(M = Fe, Co, Ni) catalysts with low Au loading amount of 0.5 wt% were synthesized in this research. Addition of transition metal oxides promotes electron transfer and generation of the Au^δ−–Ov–Ti³⁺interface

https://doi.org/10.1016/j.gee.2021.09.006

Citation:W. Yang, M. Fu, C. Yang, Y. Zhang, C. Shen,Green Energy Environ. 8 (2023) 785-797.

MOF-derived Zn–Co–Ni sulfides with hollow nanosword arrays for high-efficiency overall water and urea electrolysis

Xiaoqiang Du*, Yangyang Ding, Xiaoshuang Zhang

This research will provide certain reference to design and synthesize MOF-derived trimetallic sulfides as efficient and stable electrocatalyst for enhanced water and urea electrolysis.

https://doi.org/10.1016/j.gee.2021.09.007

Citation:X. Du, Y. Ding, X. Zhang,Green Energy Environ. 8 (2023) 798-811.

A fast and in-depth self-reconstruction of anion ligands optimized CoFe-based pre-catalysts for water oxidation

Qiuyan Jin, Hao Cui*, Chengxin Wang

PO₄³⁻optimized pre-catalyst is able to achieve a rapid and deep reconstruction, which generates active CoOOH species at a low potential of 1.4 V and deeply transforms into nanosheets with enriched active species. The evolved catalysts exhibit the greatly improved OER catalytic activity with decent durability.

https://doi.org/10.1016/j.gee.2021.10.002

Citation:Q. Jin, H. Cui, C. Wang,Green Energy Environ. 8 (2023) 812-819.

Accelerated prediction of Cu-based single-atom alloy catalysts for CO₂reduction by machine learning

Dashuai Wang¹, Runfeng Cao¹, Shaogang Hao*, Chen Liang, Guangyong Chen, Pengfei Chen, Yang Li, Xiaolong Zou*

Based on screening of optimal CO adsorption sites with high selectivity over hydrogen evolution reaction, Cu-based single-atom alloys, as promising catalysts for CO₂reduction reaction, are obtained by machine learning and high-throughput first-principles calculations.

https://doi.org/10.1016/j.gee.2021.10.003

Citation:D. Wang, R. Cao, S. Hao, C. Liang, G. Chen, P. Chen, Y. Li, X. Zou,Green Energy Environ. 8 (2023) 820-830.

Oxygen vacancy defects engineering on Cu-doped Co₃O₄for promoting effective COS hydrolysis

Guanyu Mu, Yan Zeng, Yong Zheng, Yanning Cao*, Fujian Liu, Shijing Liang*, Yingying Zhan, Lilong Jiang

A series of Cu-doped Co₃O₄catalysts is prepared by a solvothermal method. Cu-doped Co₃O₄with the enhanced surface defect concentrations show high COS hydrolysis activities. Moreover, the degree of sulfation is reduced after Cu doped which makes the catalyst with higher stability.

https://doi.org/10.1016/j.gee.2021.11.001

Citation:G. Mu, Y. Zeng, Y. Zheng, Y. Cao, F. Liu, S. Liang, Y. Zhan, L. Jiang,Green Energy Environ. 8 (2023) 831-841.

Synthesis of MgO-doped ordered mesoporous carbons by Mg²⁺-tannin coordination for efficient isomerization of glucose to fructose

Junyan Fu¹, Feng Shen¹, Xiaoning Liu, Xinhua Qi*

In this work, MgO in-situ doped ordered mesoporous carbon (OMC@MgO) with high activity towards glucose isomerization was synthesized from sustainable tannin via formaldehyde-free self-assembly strategy.

https://doi.org/10.1016/j.gee.2021.11.010

Citation:J. Fu, F. Shen, X. Liu, X. Qi,Green Energy Environ. 8 (2023) 842-851.

Deep eutectic solvent-induced synthesis of Ni–Fe catalyst with excellent mass activity and stability for water oxidation

Ruichang Xue, Mengwei Guo, Zhuoming Wei, Qibo Zhang*

Well-defined Ni-Fe nanoparticles in-situ developed on a planar Fe substrate (Ni-Fe NPs/Fe) is fabricated via a facial one-step galvanic replacement reaction (GRR) carried out in a Ethaline-based deep eutectic solvent (DES), which exhibit excellent catalytic activity and robust stability for oxygen evolution reaction (OER).

https://doi.org/10.1016/j.gee.2021.11.006

Citation:R. Xue, M. Guo, Z. Wei, Q. Zhang,Green Energy Environ. 8 (2023) 852-863.

Heterostructuring noble-metal-free 1T" phase MoS₂with g-C₃N₄hollow nanocages to improve the photocatalytic H₂evolution activity

Yanjun Xue, Yinghong Ji, Xinyu Wang, Huanli Wang*, Xiaobo Chen*, Xiaoli Zhang, Jian Tian*

This work successfully designed a novel 1T"-MoS₂/g-C₃N₄NC composite photocatalyst by loading 1T"-MoS₂on the g-C₃N₄with nanocage structures. The synthesized 1T"-MoS₂/g-C₃N₄NC composite present outstanding photocatalytic hydrogen production performance compared with g-C₃N₄NCs and g-C₃N₄NSs.

https://doi.org/10.1016/j.gee.2021.11.002

Citation:Y. Xue, Y. Ji, X. Wang, H. Wang, X. Chen, X. Zhang, J. Tian,Green Energy Environ. 8 (2023) 864-873.

Electrodeposited 3D hierarchical NiFe microflowers assembled from nanosheets robust for the selective electrooxidation of furfuryl alcohol

Biying Liu, Man Zhang, Yaoyu Liu, Yuchen Wang, Kai Yan*

This work reported an efficient electrocatalyst based on NiFe microflower facilely prepared by one-step electrodeposition strategy robust for the electrocatalytic oxidation of biomass-derived FFA (FFAOR) towards FurAc.

https://doi.org/10.1016/j.gee.2021.11.008

Citation:B. Liu, M. Zhang, Y. Liu, Y. Wang, K. Yan,Green Energy Environ. 8 (2023) 874-882.

CoSnO₃/C nanocubes with oxygen vacancy as high-capacity cathode materials for rechargeable aluminum batteries

Shuainan Guo¹, Mingquan Liu¹, Haoyi Yang, Xin Feng, Ying Bai, Chuan Wu*

Herein, CoSnO₃/C nanocubes with oxygen vacancy have been successfully prepared and investigated as high-capacity cathode material for rechargeable aluminum batteries for the first time.

https://doi.org/10.1016/j.gee.2021.11.009

Citation:S. Guo, M. Liu, H. Yang, X. Feng, Y. Bai, C. Wu,Green Energy Environ. 8 (2023) 883-892.

Imidazolium group prompted alkaline anion-exchange membrane with high performance for efficient electrochemical CO₂conversion

Min Wang¹, Qianqian Zou¹, Xueqi Dong, Nengneng Xu, Rong Shao*, Jianfei Ding, Yidong Zhang, Jinli Qiao*

A sequence of innovative PVA/PQ44-OHg^–alkaline anion-exchange membranes have been prepared using polymer PVA and PQ44, which exhibited superior hydroxide conductivity (21.47 mS cm^-1) and robust alkaline stability, as well as excellent thermal stability with onset degradation temperature high above 170 °C.

https://doi.org/10.1016/j.gee.2021.12.003

Citation:M. Wang, Q. Zou, X. Dong, N. Xu, R. Shao, J. Ding, Y. Zhang, J. Qiao,Green Energy Environ. 8 (2023) 893-903.

Plasma treated M1 MoVNbTeO_x–CeO₂composite catalyst for improved performance of oxidative dehydrogenation of ethan

Shuairen Qian¹, Yuxin Chen¹, Binhang Yan, Yi Cheng*

Plasma treatment to enhance catalytic performance of M1-CeO₂catalyst and convert electrical energy into chemical energy in materials.

https://doi.org/10.1016/j.gee.2022.01.001

Citation:S. Qian, Y. Chen, B. Yan, Y. Cheng,Green Energy Environ. 8 (2023) 904-914.

Silk nanofibril as nanobinder for preparing COF nanosheet-based proton exchange membrane

Ping Li, Ningxin Zhang, Xuan Li, Shaokun Tang*

1D flexible SNF from silk cocoon is utilized as nanobinder to link 2D porous SCON into robust SCON-based membrane. The crystalline porous nanochannels with abundant –SO₃H groups and interfacial H-bond pathways permit high-rate proton transfer.

https://doi.org/10.1016/j.gee.2022.05.008

Citation:P. Li, N. Zhang, X. Li, S. Tang,Green Energy Environ. 8 (2023) 915-926.

Enhanced hydrodeoxygenation of lignin-derived anisole to arenes catalyzed by Mn-doped Cu/Al₂O₃

Xiaofei Wang, Shixiang Feng, Yue Wang, Yujun Zhao, Shouying Huang, Shengping Wang, Xinbin Ma*

In this work, Mn-doped Cu/Al₂O₃developed from LDH precursor was synthesized and applied in liquid-phase HDO of lignin-derived anisole. It was found that the doping of Mn into Cu/ Al₂O₃significantly enhanced selectivity to arenes. The promoting effect of MnO_xfor active sites reconstruction and HDO activity improvement was investigated in details.

https://doi.org/10.1016/j.gee.2021.12.004

Citation:X. Wang, S. Feng, Y. Wang, Y. Zhao, S. Huang, S. Wang, X. Ma,Green Energy Environ. 8 (2023) 927-937.

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